Abstract
Ultrasound (US) and other non-traditional energy sources (for instance microwave (MW)) are widely used to increase the rate of chemical reactions, to prepare nanoparticles, to extract natural products etc. In all such cases, the scaling-up of the process must have a defined economic constraint, which generally can be reduced to the evaluation of the parameter RC, which is the ratio between the raw energy cost to produce US (or MW) and the total production cost for unit mass of product. The paper gives a basic correlation among the different parameters to evaluate RC both for processes using only US (or MW and other not traditional sources) and those with mixed energy sources.References
Cravotto G, Cintas P. The Combined Use of Microwaves and Ultrasound: Improved Tools in Process Chemistry and Organic Synthesis. Chem - A Eur J. 2007; 13: 1902-1909. doi:10.1002/chem.200601845.
Pradhan SR. Colmenares-Quintero RF, Colmenares Quintero JC. Designing Microflowreactors for Photocatalysis Using Sonochemistry: A Systematic Review Article. Molecules 2019; 24: 3315. doi:10.3390/molecules24183315.
Prajapati SM, Patel KD, Vekariya RH, Panchal SN, Patel HD. Recent advances in the synthesis of quinolines: a review. RSC Adv. 2014; 4: 24463-24476. doi:10.1039/C4RA01814A.
Pirola C, Bianchi CL, Di Michele A, Diodati P, Boffito D, Ragaini V. Ultrasound and microwave assisted synthesis of high loading Fe-supported Fischer-Tropsch catalysts. Ultrason Sonochem. 2010; 17: 610-616. doi:10.1016/j.ultsonch.2009.11.004.
Elwakeel KZ, Al-Bogami AS, Guibal E. 2-Mercaptobenzimidazole derivative of chitosan for silver sorption - Contribution of magnetite incorporation and sonication effects on enhanced metal recovery. Chem Eng J. 2021; 403: 126265. doi:10.1016/j.cej.2020.126265.
Elwakeel KZ, Shahat A, Al-Bogami AS, Wijesiri B, Goonetilleke A. The synergistic effect of ultrasound power and magnetite incorporation on the sorption/desorption behavior of Cr(VI) and As(V) oxoanions in an aqueous system. J Colloid Interface Sci. 2020; 569: 76-88. doi:10.1016/j.jcis.2020.02.067.
Elwakeel KZ, Shahat A, Khan ZA, Alshitari W, Guibal E. Magnetic metal oxide-organic framework material for ultrasonic-assisted sorption of titan yellow and rose bengal from aqueous solutions. Chem Eng J. 2020; 392: 123635. doi:10.1016/j.cej.2019.123635.
Pérez L, Ledón Y, Santana K, Domínguez E, Pérez M. Introduction of SOFC Technology into Cuban Energy Sector: Technical and Sustainability Analysis. J Chem Eng Res Updat. 2016; 2: 36-50. doi:10.15377/2409-983X.2015.02.02.1.
Vázquez-Román R, Inchaurregui-Méndez J, Ponce-Ortega J, Mannan M. A Heat Exchanger Networks Synthesis Approach Based on Inherent Safety. J Chem Eng Res Updat. 2015; 2: 22-29. doi:10.15377/2409-983X.2015.02.01.3.
Mason TJ, Lorimer JP. Practical Sonochemistry. Ellis Horwood, 1991.
Brochette S, Descotes G, Bouchu A, Queneau Y, Monnier N, Pétrier C. Effect of ultrasound on KSF/O mediated glycosylations. J Mol Catal A Chem. 1997; 123: 123-130. doi:10.1016/S1381-1169(97)00038-1.
Zhang F, Sun J, Gao D, Li Y, Zhang Y, Zhao T, Chen X. An efficient and convenient procedure for the synthesis of 2- alkyl-2-alkoxy-1,2-di(furan-2-yl)ethanone under ultrasound in the presence of solid-liquid phase transfer catalysis conditions. Ultrason Sonochem. 2007; 14: 493-496. doi:10.1016/j.ultsonch.2007.02.004.
Ding L, Wang W, Zhang A. Synthesis of 1,5-dinitroaryl-1,4- pentadien-3-ones under ultrasound irradiation. Ultrason Sonochem. 2007; 14: 563-567. doi:10.1016/j.ultsonch.2006.09.008.
Wang S-X, Li Z-Y, Zhang J-C, Li J-T. The solvent-free synthesis of 1,4-dihydropyridines under ultrasound irradiation without catalyst. Ultrason Sonochem. 2008; 15: 677-680. doi:10.1016/j.ultsonch.2008.02.009.
Rodrigues S, Pinto G, Fernandes F. Optimization of ultrasound extraction of phenolic compounds from coconut (Cocos nucifera) shell powder by response surface methodology. Ultrason Sonochem. 2008; 15: 95-100. doi:10.1016/j.ultsonch.2007.01.006.
Kristl M, Drofenik M. Sonochemical synthesis of nanocrystalline mercury sulfide, selenide and telluride in aqueous solutions. Ultrason Sonochem. 2008; 15: 695-699. doi:10.1016/j.ultsonch.2008.02.007.
Nickel K, Neis U. Ultrasonic disintegration of biosolids for improved biodegradation. Ultrason Sonochem. 2007; 14: 450-455. doi:10.1016/j.ultsonch.2006.10.012.
Bjorndalen N, Islam MR. The effect of microwave and ultrasonic irradiation on crude oil during production with a horizontal well. J Pet Sci Eng. 2004; 43: 139-150. doi:10.1016/j.petrol.2004.01.006.
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