Abstract
The negative environmental impacts of internal combustion engines have changed the interest of scientists towards fuel cell engines. Using Proton Exchange Membrane (PEM) fuel cell operating under higher temperature solves some of the well-known low temperature problems. In this study, a numerical simulation has been carried out using a three-dimensional model in COMSOL to evaluate the performance of high temperature PEM (HT-PEM) fuel cell under different conditions. The obtained polarization curve for selected voltage was compared with published experimental data, and it shows a good agreement. The simulation results in terms of reactants (hydrogen and oxygen) concentrations and water production on the anode and cathode sides is presented. The influences of some key parameters on HT-PEM fuel cell performance were investigated. It was found that as the temperature and pressure increase, the performance of the HT-PEM fuel cell improves. The enhanced reaction rate and a better supply of reactants were observed to have a positive influence on HT-PEM fuel cell performance. Additionally, the results show that considering a higher permeation rate on the gas diffusion layer can enhance the performance of the fuel cell. This work provides a guideline to design and optimize a HT-PEM fuel cell with a better capability.
References
Resitotlu IA, Altinisik K, Keskin A. The pollutant emissions from diesel-engine vehicles and exhaust aftertreatment systems. Clean Technol Environ Policy 2015; 17: 15-27. https://doi.org/10.1007/s10098-014-0793-9
Shafiee S, Topal E. When will fossil fuel reserves be diminished ? Energy Policy 2009; 37: 181-9. https://doi.org/10.1016/j.enpol.2008.08.016
Das V, Padmanaban S, Venkitusamy K. Recent advances and challenges of fuel cell based power system architectures and control - A review. Renew Sustain Energy Rev 2017; 73: 10-8. https://doi.org/10.1016/j.rser.2017.01.148
O’hayre R, Cha SW, Colella W, Prinz FB. Fuel Cell Fundamentals. John Wiley & Sons 2016: 603. https://doi.org/10.1002/9781119191766
Miller M, Bazylak A. A review of polymer electrolyte membrane fuel cell stack testing. J Power Sources 2011; 196: 601-13. https://doi.org/10.1016/j.jpowsour.2010.07.072
Chippar P, Oh K, Kim D, Hong T, Kim W, Ju H. Coupled mechanical stress and multi-dimensional CFD analysis for high temperature proton exchange membrane fuel cells (HT-PEMFCs). Int J Hydrogen Energy 2012; 38: 7715-24. https://doi.org/10.1016/j.ijhydene.2012.07.122
Authayanun S, Im-orb K, Arpornwichanop A. A review of the development of high temperature proton exchange membrane fuel cells. Chinese J Catal 2015; 36: 473-83. https://doi.org/10.1016/S1872-2067(14)60272-2
Zhang C, Zhou W, Mousavi M, Wang Y, Hwa S. Determination of the optimal operating temperature range for high temperature PEM fuel cell considering its performance , CO tolerance and degradation. Energy Convers Manag 2015; 105: 433-41. https://doi.org/10.1016/j.enconman.2015.08.011
Sousa T, Mamlouk M, Scott K. An isothermal model of a laboratory intermediate temperature fuel cell using PBI doped phosphoric acid membranes. Chem Eng Sci 2010; 10: 2513-30. https://doi.org/10.1016/j.ces.2009.12.038
Xia L, Zhang C, Hu M, Jiang S. Investigation of parameter effects on the performance of high-temperature PEM fuel cell. Int J Hydrogen Energy 2018; 43: 23441-9. https://doi.org/10.1016/j.ijhydene.2018.10.210
Araya SS, Zhou F, Liso V, Sahlin SL, Vang JR, Thomas S. A comprehensive review of PBI-based high temperature PEM fuel cells. Int J Hydrogen Energy 2016,41: 21310-44. https://doi.org/10.1016/j.ijhydene.2016.09.024
Chandan A, Hattenberger M, El-kharouf A, Du S, Dhir A, Self V, et al. High temperature (HT) polymer electrolyte membrane fuel cells (PEMFC) A review. J Power Sources 2013; 231: 264-78. https://doi.org/10.1016/j.jpowsour.2012.11.126
Rosli RE, Sulong AB, Daud WRW, Zulkifley MA. A review of high-temperature proton exchange membrane fuel cell (HT-PEMFC) system. Int J Hydrogen Energy 2017; 42: 9293-9314. https://doi.org/10.1016/j.ijhydene.2016.06.211
Abdul Rasheed RK, Liao Q, Caizhi Z, Chan SH. A review on modelling of high temperature proton exchange membrane fuel cells (HT-PEMFCs). Int J Hydrogen Energy 2017; 42: 3142-65. https://doi.org/10.1016/j.ijhydene.2016.10.078
Liu Y, Lehnert W, Janßen H, Can R. A review of high-temperature polymer electrolyte membrane fuel-cell (HT-PEMFC) -based auxiliary power units for diesel-powered road vehicles. J Power Sources 2016; 311: 91-102. https://doi.org/10.1016/j.jpowsour.2016.02.033
Orfanidi A, Daletou MK, Neophytides SG. Applied Catalysis B : Environmental Preparation and characterization of Pt on modified multi-wall carbon nanotubes to be used as electrocatalysts for high temperature fuel cell applications. J Appl Catal B Environ 2011; 106: 379-89. https://doi.org/10.1016/j.apcatb.2011.05.043
Kongstein OEÃ, Berning T, Børresen B, Seland F, Tunold R. Polymer electrolyte fuel cells based on phosphoric acid doped polybenzimidazole (PBI) membranes. Energy 2007; 32: 418-22. https://doi.org/10.1016/j.energy.2006.07.009
Zhou F, Araya SS, Grigoras IF, Andreasen SJ, Kær SK. Performance Degradation Tests of Phosphoric Acid Doped Polybenzimidazole Membrane Based High Temperature Polymer Electrolyte Membrane Fuel Cells. J Fuel Cell Sci Technol 2014; 12: 1-9. https://doi.org/10.1115/FuelCell2014-6358
Muthuraja P, Prakash S, Susaimanickam A, Manisankar P. Potential membranes derived from poly (aryl hexafluoro sulfone benzimidazole) and poly (aryl hexafluoro ethoxy benzimidazole) for high-temperature PEM fuel cells. Int J Hydrogen Energy 2018; 43: 21732-41. https://doi.org/10.1016/j.ijhydene.2018.03.058
Cheddie D, Munroe N. Parametric model of an intermediate temperature PEMFC. J Power Sources 2006; 156: 414-23. https://doi.org/10.1016/j.jpowsour.2005.06.010
Cheddie DF, Munroe NDH. A two-phase model of an intermediate temperature PEM fuel cell. Int J Hydrogen Energy 2007; 32: 832-41. https://doi.org/10.1016/j.ijhydene.2006.10.061
Siegel C, Bandlamudi G, Heinzel A. Numerical Simulation of a High-Temperature PEM (HTPEM) Fuel Cell. Proc COMSOL Users Conf 2007: 1-7.
Siegel C, Bandlamudi G, Heinzel A. Systematic characterization of a PBI/H3PO4 sol-gel membrane - Modeling and simulation. J Power Sources 2011; 196: 2735-49. https://doi.org/10.1016/j.jpowsour.2010.11.028
Ubong EU, Shi Z, Wang X. Three-Dimensional Modeling and Experimental Study of a High Temperature PBI-Based PEM Fuel Cell. J Electrochem Soc 2009; 156: B1276- B1282. https://doi.org/10.1149/1.3203309
Shamardina O, Chertovich A, Kulikovsky AA, Khokhlov AR. A simple model of a high temperature PEM fuel cell. Int J Hydrogen Energy 2010; 35: 9954-62. https://doi.org/10.1016/j.ijhydene.2009.11.012
Peng J, Lee SJ. Numerical simulation of proton exchange membrane fuel cells at high operating temperature. J Power Sources 2006; 162: 1182-91. https://doi.org/10.1016/j.jpowsour.2006.08.001
Reddy EH, Monder DS, Jayanti S. Parametric study of an external coolant system for a high temperature polymer electrolyte membrane fuel cell. Appl Therm Eng 2013; 58: 155-64. https://doi.org/10.1016/j.applthermaleng.2013.04.013
Kvesić M, Reimer U, Froning D, Lüke L, Lehnert W, Stolten D. 3D modeling of a 200 cm2 HT-PEFC short stack. Int J Hydrogen Energy 2012; 37: 2430-9. https://doi.org/10.1016/j.ijhydene.2011.10.055
Lüke L, Janßen H, Kvesić M, Lehnert W, Stolten D. Performance analysis of HT-PEFC stacks. Int J Hydrogen Energy 2012; 37: 9171-81. https://doi.org/10.1016/j.ijhydene.2012.02.190
Sousa T, Mamlouk M, Scott K. A Non-isothermal model of a Laboratory Intermediate Temperature Fuel Cell using PBI doped Phosphoric Acid Membranes. J Fuel Cells 2011; 44. https://doi.org/10.1002/fuce.200900178
Jiao K, Zhou Y, Du Q, Yin Y, Yu S, Li X. Numerical simulations of carbon monoxide poisoning in high temperature proton exchange membrane fuel cells with various flow channel designs. Appl Energy 2013; 104: 21-41. https://doi.org/10.1016/j.apenergy.2012.10.059
Salomov UR, Chiavazzo E, Fasano M, Asinari P. Pore- and macro-scale simulations of high temperature proton exchange fuel cells (HTPEMFC) and possible strategies for enhancing durability. Int J Hydrogen Energy 2017; 42: 26730-43. https://doi.org/10.1016/j.ijhydene.2017.09.011
Ubeda D, Canizares P, Ferreira-Aparicio P, Antonio MC, Lobato J, Manuel AR. Life test of a high temperature PEM fuel cell prepared by electrospray. Int J Hydrogen Energy 2016; 41: 20294-304. https://doi.org/10.1016/j.ijhydene.2016.09.109
Yang Y, Zhang X, Guo L, Liu H. Degradation mitigation effects of pressure swing in proton exchange membrane fuel cells with dead-ended anode. Int J Hydrogen Energy 2017; 42: 24435-47. https://doi.org/10.1016/j.ijhydene.2017.07.223
Reimer U, Schumacher B, Lehnert W. Accelerated Degradation of High-Temperature Polymer Electrolyte Fuel Cells: Discussion and Empirical Modeling. J Electrochem Soc 2015; 162: F153-64. https://doi.org/10.1149/2.0961501jes
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
Copyright (c) 2021 Journal of Advanced Thermal Science Research